碩士生導(dǎo)師、教授名單

楊科

發(fā)布時(shí)間:2019-03-04瀏覽次數(shù):4741

楊科  副研究員

聯(lián)系方式keyang@cczu.edu.cn


教育經(jīng)歷:

2004年-2008年,江蘇師范大學(xué),學(xué)士

2008年-2011年,江蘇師范大學(xué),有機(jī)化學(xué)碩士

2011年-2014年,南京大學(xué),有機(jī)化學(xué)博士


工作經(jīng)歷:

2014年-2015年,南京大學(xué)化學(xué)與生物醫(yī)學(xué)科學(xué)研究所,博士后

2015年-2017年,美國(guó)印第安納大學(xué)-普渡大學(xué)印第安納波利斯分校,訪問學(xué)者

2017年至今,常州大學(xué),助理研究員、副研究員


個(gè)人榮譽(yù):

2018年江蘇省“雙創(chuàng)博士”

2019年江蘇省“六大人才高峰”高層次人才

2023年常州市第17屆自然科學(xué)優(yōu)秀學(xué)術(shù)論文三等獎(jiǎng)


社會(huì)兼職(社會(huì)兼職填是否擔(dān)任過專業(yè)雜志編委、專業(yè)委員會(huì)委員、專業(yè)協(xié)會(huì)會(huì)員等)

(1) Green Synth. Catal. 青年編委

(2) Org. Chem. Front. GreenChem., Chem. Commun., J. Org. Chem.等雜志審稿人


研究方向:

過渡金屬催化、C-H鍵活化、綠色有機(jī)合成方法學(xué),藥物設(shè)計(jì)合成以及相關(guān)雜質(zhì)分離鑒定


教學(xué)科研項(xiàng)目:

2017年國(guó)家自然科學(xué)基金青年項(xiàng)目

2019年江蘇省“六大人才高峰”高層次人才項(xiàng)目

2019年度常州大學(xué)大學(xué)生課外創(chuàng)新創(chuàng)業(yè)基金項(xiàng)目

2020年度江蘇省研究生培養(yǎng)創(chuàng)新工程項(xiàng)目

2021年度常州大學(xué)大學(xué)生課外創(chuàng)新創(chuàng)業(yè)基金項(xiàng)目

2021年原料藥JC-5411雜質(zhì)鑒定項(xiàng)目

2021年JN-2528化合物研究項(xiàng)目

2022年度江蘇省研究生培養(yǎng)創(chuàng)新工程項(xiàng)目

2022年度常州大學(xué)大學(xué)生課外創(chuàng)新創(chuàng)業(yè)基金項(xiàng)目

2023年度江蘇省協(xié)調(diào)同創(chuàng)新人才支持項(xiàng)目


論文發(fā)表(一作或通訊):

(1)K. Yang, Q. Li, Y. Liu, G. Li*, H. Ge*. Catalytic C?H arylation of aliphatic aldehydes enabled by a transient ligand.J. Am. Chem. Soc.2016, 138, 12775. (Highlight in Synform, 2017, 01, A7-A9). (SCI一區(qū))

(2)L. Pan,§K. Yang§, G. Li*, H. Ge*. Palladium-catalyzed site-selective arylation of aliphatic ketones enabled by a transient ligand. Chem. Commun.2018, 54, 2759. (§:共同一作)

(3) K.Yang,* H. Zhang, B. Niu, T. Tang, H. Ge*. Benzisothiazol-3-ones through a metal-free intramolecular N?S bond formation. Eur. J. Org. Chem.2018, 2018, 5520.

(4)Y. Yin, H. Liu, T. Xiao, X. Sun, K. Yang,* Z. Li,* Synthesis and crystal structure of trifluoromethyl-containing bendamustine hydrochloride. J. Chem. Res.2019, 43, 386.

(5)B. Niu, K. Yang,* B. Lawrence, H. Ge,* Transient ligand-enabled transition metal-catalyzed C?H functionalization. ChemSusChem2019, 12, 2955. (SCI一區(qū))

(6) K. Yang,* Y. Li, Z. Ma, L. Tang, Y. Yin, H. Zhang, Z. Li,* X. Sun,* Metal-free C?S bond cleavage to access N-substituted acrylamide and β-aminopropanamide.Eur. J. Org. Chem.2019, 2019, 5812. (Highlight in ChemViews Magazine).

(7) K. Yang,* B. Niu, Z. Ma, H. Wang, B. Lawrence, H. Ge,* Silver-promoted site-selective intramolecular cyclization of 2-methylthiobenzamide through α-C(sp3)?H functionalization. J. Org. Chem. 2019, 84, 14045.

(8) K. Yang,* M. Song, Z. Ma, Y. Li, Z.-Y. Li,* X. Sun,* The decarboxylative C?H heteroarylation of azoles catalysed by nickel catalysts to access unsymmetrical biheteroaryls. Org. Chem. Front.2019, 6, 3996. (SCI一區(qū))

(9) K. Yang, M. Song, H. Liu, H. Ge,* Palladium-catalyzed direct asymmetric C?H bond functionalization enabled by the directing group strategy. Chem. Sci.2020, 11, 12616. (SCI一區(qū))

(10) K. Yang,* M. Song, A. I. M. Ali, S. M. Mudassir, H. Ge,* Recent advances in the application of Selectfluor as a "fluorine-free" functional reagent in organic synthesis. Chem. Asian J.2020, 15, 729.

(11) K. Yang, Z. Ma, H.-X. Tong, X.-Q. Sun,* X.-Y. Hu, Z.-Y. Li,* Asymmetric Michael addition reactions catalyzed by a novel upper-rim functionalized calix[4]squaramide organocatalyst. Chin. Chem. Lett.2020, 31, 3259. (SCI一區(qū))

(12)Y. Li, Q. Hu, F. Zhang, Y.-Z. Li, X. Sun,* K. Yang,* Metal-free selective C-S bond cleavage of thioethers to access β-alkoxy carbonyl compounds. ChemistrySelect2021, 6, 6268.

(13)Z. Ma, Y. Li, X. Sun, K. Yang,* Y.-Z. Li,* Calixarene promoted transition-metal-catalyzed reactions. Chin. J. Org. Chem. 2021, 41, 2188.

(14) K. Yang,* S. Dai, Z. Li, Y.-Z. Li, X. Sun,* Amide-assisted α-C(sp3)–H acyloxyation of organic sulfides to access α-acyloxy sulfides. Org. Chem. Front.2021, 8, 4974.(SCI一區(qū))

(15) K. Yang,* Y. Li, M. Song, S. Dai, Z.-Y. Li,* X. Sun, Metal-free direct C(sp3)-H functionalization of 2-alkylthiobenzoic acid to access 1,3-benzooxathiin-4-one. Chin. Chem. Lett.2021, 32, 146.

(16) K. Yang, Z. Li, Q. Hu, M. Elsaid, C. Liu, J. Chen and H. Ge,* Recent Strategies in Nickel-Catalyzed C–H Bond Functionalization for Nitrogen-Containing Heterocycles. Catalysts2022, 12, 1163.

(17) K. Yang, Z. Li, C. Liu, Y. Li, Q. Hu, M. Elsaid, B. Li, J. Das, Y. Dang, D. Maiti, H. Ge,* Ligand-promoted palladium-catalyzed β-methylene C–H arylation of primary aldehydes. Chem. Sci.2022, 13, 5938. (SCI一區(qū))

(18)S. Dai, K. Yang,* Y. Luo, Z. Xu, Z. Li, Z.-Y. Li, B. Li, X. Sun,* Metal-free and Selectfluor-mediated diverse transformations of 2-alkylthiobenzamides to access 2,3-dihydrobenzothiazin-4-ones, benzoisothiazol-3-ones and 2-alkylthiobenzonitriles. Org. Chem. Front.2022, 9, 4016. (SCI一區(qū))

(19)X.-Q. Feng, H.-C. Wang, Z. Li, L. Tang, X. Sun, K. Yang,* Transition-metal-catalyzed remote C–H functionalization of thioethers. RSC Adv. 2022, 12, 10835.

(20) Y. Wu, Z. Ma, J. Shi, X. Sun, K. Yang,* Z.-Y. Li,* Supramolecular interaction controlled and calix[4]arene ligand assisted Pd-catalyzed C(sp3)?H arylation of aliphatic aldehydes. Chin. Chem. Lett.2022, 33, 5116. (SCI一區(qū))

(21) L. Tang, Q. Hu, K. Yang,* M. Elsaid, C. Liu, H. Ge,* Recent advances in direct α-C(sp3)–H bond functionalization of thioethers. Green Synth. Catal.2022, 3, 203.

(22) M. Song, Q. Hu, Z.-Y. Li, X. Sun,K. Yang,* NFSI-catalyzed S?S bond exchange reaction for the synthesis of unsymmetrical disulfides.Chin. Chem. Lett.2022, 33, 4269. (SCI一區(qū))

(23) K. Yang,* Q. Li, Z. Li, X. Sun, Transition-metal-free C–S bond cleavage and transformation of organosulfur compounds. Chem. Commun. 2023,59, 5343.

(24) K. Yang,* Q. Hu, Q. Li, J. Liu, Z.-Y. Li, B. Li, X. Sun, Metal-free and NBS-mediated direct thiol-disulfide exchange reaction to access unsymmetrical disulfides. Eur. J. Org. Chem.2023, e202300394.

(25)Z. Wang, Y. Li, Jing Shi, X. Sun, T. Xiao, K. Yang,* Z.-Y. Li,* A fluorescent probe for Al3+ based on calix[4]arene containing salicylaldehyde-derived schiff base. Eur. J. Org. Chem.2023, e202300639.

(26) K. Yang,* Y. Luo, Q. Hu, M. Song, J. Liu, Z. Li, B. Li,* X. Sun, Selective C(sp3)–S bond cleavage of thioethers to build up unsymmetrical disulfides. J. Org. Chem.2023, 88, 13699.

(27) K. Yang, H. Ge,* Pd(II)-catalyzed ligand-promoted γ-C(sp2)?H arylation of free allylamines. Chem Catal. 2023, 3, 100818.

(28) Z. Xu, Z.Li, C. Liu, K. Yang,* H. Ge,* Palladium-catalyzed β-C(sp3)–H bond arylation of tertiaryaldehydes facilitated by 2-pyridone ligands. Molecules2024, 29, 259.

(29) K. Wang, L. Wan, J. Wang, C. Zhou, K. Yang,* L. Zhou, B. Li*Multifunctional 2-(2'-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs.Chin. Chem. Lett.2024, accepted. (SCI一區(qū))


授權(quán)專利:

2017年至今共授權(quán)中國(guó)發(fā)明專利25項(xiàng),德國(guó)專利1項(xiàng)。


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